[root@CentOS ~]# vi /etc/profile

在文件末尾加上如下两行代码

PATH=/usr/local/webserver/php/bin:$PATH
export PATH 

# /etc/profile

# System wide environment and startup programs, for login setup
# Functions and aliases go in /etc/bashrc

# It's NOT a good idea to change this file unless you know what you
# are doing. It's much better to create a custom.sh shell script in
# /etc/profile.d/ to make custom changes to your environment, as this
# will prevent the need for merging in future updates.

pathmunge () {
    case ":${PATH}:" in
        *:"$1":*)
            ;;
        *)
            if [ "$2" = "after" ] ; then
                PATH=$PATH:$1
            else
                PATH=$1:$PATH
            fi
    esac
}


if [ -x /usr/bin/id ]; then
    if [ -z "$EUID" ]; then
        # ksh workaround
        EUID=`id -u`
        UID=`id -ru`
    fi
    USER="`id -un`"
    LOGNAME=$USER
    MAIL="/var/spool/mail/$USER"
fi

# Path manipulation
if [ "$EUID" = "0" ]; then
    pathmunge /sbin
    pathmunge /usr/sbin
    pathmunge /usr/local/sbin
else
    pathmunge /usr/local/sbin after
    pathmunge /usr/sbin after
    pathmunge /sbin after
fi

HOSTNAME=`/bin/hostname 2>/dev/null`
HISTSIZE=1000
if [ "$HISTCONTROL" = "ignorespace" ] ; then
    export HISTCONTROL=ignoreboth
else
    export HISTCONTROL=ignoredups
fi

export PATH USER LOGNAME MAIL HOSTNAME HISTSIZE HISTCONTROL

# By default, we want umask to get set. This sets it for login shell
# Current threshold for system reserved uid/gids is 200
# You could check uidgid reservation validity in
# /usr/share/doc/setup-*/uidgid file
if [ $UID -gt 199 ] && [ "`id -gn`" = "`id -un`" ]; then
    umask 002
else
    umask 022
fi

for i in /etc/profile.d/*.sh ; do
    if [ -r "$i" ]; then
        if [ "${-#*i}" != "$-" ]; then
            . "$i"
        else
            . "$i" >/dev/null 2>&1
        fi
    fi
done

unset i
unset pathmungePATH=/usr/local/webserver/php/bin:$PATH 

export PATH 

要是刚才的修改马上生效，需要执行以下代码 

[root@CentOS ~]# source /etc/profile 

方法二：在用户目录下的.bash_profile文件中增加变量【对单一用户生效（永久的）】

用VI在用户目录下的.bash_profile文件中增加变量，改变量仅会对当前用户有效，并且是“永久的”。具体操作和方法1一样，这里就不在列举代码了。

方法三：直接运行export命令定义变量【只对当前shell（BASH）有效（临时的）】

在shell的命令行下直接使用[export变量名=变量值]定义变量，该变量只在当前的shell（BASH）或其子shell（BASH）下是有效的，shell关闭了，变量也就失效了，再打开新shell时就没有这个变量，需要使用的话还需要重新定义。例如

export PATH=/usr/local/webserver/php/bin:$PATH